Oxido{N-[(2-oxido-1-naphthyl-κO)methylidene]asparaginato-κ2O1,N2}(1,10-phenanthroline-κ2N,N′)vanadium(IV)N,N-dimethylformamide monosolvate
نویسندگان
چکیده
منابع مشابه
Oxido{N-[(2-oxido-1-naphthyl-κO)methylidene]asparaginato-κ2 O 1,N 2}(1,10-phenanthroline-κ2 N,N′)vanadium(IV) N,N-dimethylformamide monosolvate
The tridentate Schiff base ligand of the title complex, [V(C(15)H(12)N(2)O(4))O(C(12)H(8)N(2))]·C(3)H(7)NO, was derived from the condensation of 2-hy-droxy-1-naphthaldehyde and l-asparagine. The central V(IV) atom is six-coordinated by one oxide O atom, two N atoms from 1,10-phenanthroline and one N atom and two O atoms from the Schiff base ligand in a distorted octa-hedral geometry. In the cry...
متن کامل{4-Hydroxy-N′-[(2-oxido-1-naphthyl-κO)methylidene]benzohydrazidato-κ2 N′,O}dimethyltin(IV)
Two independent but very similar mol-ecules comprise the asymmetric unit of the title compound, [Sn(CH(3))(2)(C(18)H(12)N(2)O(3))]. Each Sn atom is coordinated by two methyl groups and two O atoms and an N atom from the dinegative tridentate ligand. The resultant C(2)NO(2) donor set defines a coordination geometry inter-mediate between square-pyramidal and trigonal-pyramidal, with a small tende...
متن کامل{N′-[(2-Oxidonaphthalen-1-yl)methylidene]benzohydrazidato}(1,10-phenanthroline)copper(II) methanol monosolvate
The title mononuclear complex, [Cu(C(18)H(12)N(2)O(2))(C(12)H(8)N(2))]·CH(3)OH, contains one N'-[(2-oxidonaphthalen-1-yl)methyl-idene]benzohydrazidate ligand (L(2-)), a Cu(2+) cation, one 1,10-phenanthroline ligand and a methanol solvent mol-ecule. The Cu(II) ion adopts a CuO(2)N(3) distorted square-pyramidal coordination. An O-H⋯O hydrogen bond is formed between the methanol solvent mol-ecule ...
متن کامل1,10-Phenanthroline-5,6-dione ethanol monosolvate
In the title compound, C12H6N2O2·C2H5OH, the mol-ecule of the 1,10-phenanthroline-5,6-dione is approximately planar, with a maximum deviation of 0.051 (1) Å. In the crystal, mol-ecules are linked by O-H⋯N and weak C-H⋯O hydrogen bonds, forming supra-molecular chains propagating along [110]. π-π stacking inter-actions are observed between the pyridine rings of neighbouring chains, the centroid-c...
متن کاملAqua(2-oxido-2,2-diphenylacetato-κ2 O 1,O 2)(1,10-phenanthroline-κ2 N,N′)copper(II)
In the title mononuclear complex, [Cu(C(14)H(10)O(3))(C(12)H(8)N(2))(H(2)O)], the Cu(II) atom is five-coordinated by two N atoms from a 1,10-phenanthroline (phen) ligand, two O atoms from a benzilate ligand and one O atom from a water mol-ecule in a distorted square-pyramidal geometry. The crystal structure is stabilized via inter-molecular O-H⋯O and C-H⋯O hydrogen bonds, C-H⋯π inter-actions an...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s1600536810030126